Abstract
The present study reports about the use of fenugreek seed spent as a new and efficient biosorbent for the removal of acid blue 113 dye from aqueous media and textile industrial effluent. The spent is a low-cost by-product of nutraceutical industry. The effects of various process parameters of adsorption, such as pH, initial dye concentration, adsorbent dose, adsorbent particle size, contact time and temperature onto nutraceutical industrial fenugreek seed spent (NIFGS) have been studied. Four numbers of two-parameter and six numbers of three-parameter isotherm models were used in the analysis of adsorption equilibrium data. Kinetic studies data conformed to pseudo-second-order model. Molecular diffusion studies were carried out using Weber–Morris, Dumwald–Wagner and film diffusion models. Change in enthalpy (ΔH°), entropy change (ΔS°) and Gibbs free energy change (ΔG°) of adsorption system indicated that the process is physisorption. Scanning electron microscopy, Fourier transform infrared spectroscopy and point of zero charge were used in characterizing the adsorbent. Fractional factorial experimental design and analysis of variance along with statistically developed model for adsorption helped to predict for a maximum adsorption of 661.5 mg g−1 using NIFGS. Application of NIFGS to textile industrial effluent and scaling up of the experimental process by three orders gave encouraging results.
Highlights
It is of utmost importance as of societal concern about the large-scale depletion of natural resources as the environmental regulations which have diverted the attention of people in search for getting clean air, soil and water
Surface characterization of nutraceutical industrial fenugreek seed spent (NIFGS) done through SEM exhibited slightly porous structure (Fig. 3a)
The results of research have conclusively proven that use of Nutraceutical Industrial Spent (NIS) for the adsorption and remediation of toxic dyes from textile industrial effluent is a successful process and has significant economic payoffs
Summary
It is of utmost importance as of societal concern about the large-scale depletion of natural resources as the environmental regulations which have diverted the attention of people in search for getting clean air, soil and water. It is of great concern to reduce the consumption of water as reducing carbon footprint (Zaffalon 2010). The current value of textile industry which placed at
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