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Abstract
Abstract The MnCl(β-dik)2 complexes, where β-dik stands for an anion of acetylacetone, benzoylacetone, and dibenzoylmethane, were confirmed to have the five-coordinate structure in dichloromethane and their adduct formation constants with various donor solvents were measured. Equilibria and kinetics of substitution reactions of MnCl(β-dik)2 with other β-diketones were determined by the spectrophotometric method and the mechanism for these reaction is proposed.
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