Kinetic analysis of the thermal decomposition of pristine and γ-irradiated zinc uranyl acetate

Abstract

Thermal decomposition of pristine and γ-irradiated zinc uranyl acetate was investigated in air using isothermal and dynamic thermogravimetric techniques. The decomposition proceeded via one major process with the formation of triuranates ZnU3O10 as solid residues. Kinetic analysis of isothermal data, when compared with various solid-state reaction models, showed that the decomposition reaction is best fitted by the phase-boundary model. Kinetic analysis of the dynamic TG curves was discussed with reference to integral methods of modified Coats and Redfern equations. Kinetic and thermodynamic parameters were calculated and evaluated. IR spectroscopy and X-ray powder diffraction techniques were employed to follow the chemical composition of solid residue at different calcination temperatures. The results display that the triuranate ZnU3O10 starts forming by calcination of zinc uranyl acetate at temperatures > 300 °C and undergoes decomposition at higher temperatures (>600 °C) with the formation of U3O8. The results were evaluated regarding the utilization of zinc uranyl acetate as an important source of diuranates and triuranates.