Abstract
An adequate understanding of the kinetics of thermal decomposition is fundamental for the design of energy systems. The optimization algorithms have been widely used in the kinetic analysis of thermochemical reactions of biomass materials, for which one of the main concerns is optimization performance. The effect of kinetic parameter values on the n-th order reaction suggests that the optimization performance can be improved based on the kinetic compensation effect (KCE) by considerably narrowing search ranges for kinetic analysis. In this paper, a generalized kinetic method called ETp method is proposed based on KCE and optimization calculation. Analyses verify that the method is generally applicable for a wide variety of reaction mechanisms and kinetic models. The good performance of the method is confirmed by experimental and synthetic data.
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