Abstract

A number of equations have been proposed by workers in the field of liquid state and, upon exploration, these have been found to meet success of varying degrees. Khasare has proposed a new equation of state involving intermolecular potential with three-model parameters. This equation of state has been applied to the binary liquid mixture of benzene, tetrahydrofuran and carbon tetrachloride in 1-4 dioxane. It is observed that there is a close agreement with experimental values for ultrasonic wave velocity, molar volume and, to some degree, volume expansion coefficient. Model parameters are fairly constant over the liquid phase 10 K above m.p. and 10 K below b.p.

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