Abstract
Abstract β-Ketonitrosamines have been established as anionic synthons of the type (RCO+ −CHNHR′). The enhanced acidity of protons at the α-carbon, as well as the ease of fragmentation of the title compounds, established them as synthetic equivalents of α-methylenealkylamino anions (−CH2NHR). We now report the equivalency of β-ketonitrosamines to α-methinyl methylamino (R−CHNHCH3) and α-methinyl alkylamino (R −CHNHR′) anions.
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