Abstract

We study bridging transitions between a pair of nonplanar surfaces. We show that the transition can be described using a generalized Kelvin equationby mapping the system to a slit of finite length. The proposed equationis applied to analyze the asymptotic behavior of the growth of the bridging film, which occurs when the confining walls are gradually flattened. This phenomenon is characterized by a power-law divergence with geometry-dependent critical exponents that we determine for a wide class of walls' geometries. In particular, for a linear-wedge model, a covariance law revealing a relation between a geometric and Young's contact angle is presented. These predictions are shown to be fully in line with the numerical results obtained from a microscopic (classical) density functional theory.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.