Abstract

A novel supramolecular complex Li3Cl[(HPW12O40)(H24C12O6)3(CH3CN)2] {CR-PW12} was confirmed first to apply as a sulfur host in lithium-sulfur batteries. The {CR-PW12}@S cathode exhibits a reversible capacity of 1120 mA h g-1 at 1.0 C and excellent cycle stability.

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