Kaolin-Supported Silver Nanoparticles as an Effective Catalyst for the Removal of Methylene Blue Dye from Aqueous Solutions.

Abstract

Water contamination by organic dyes has become a reason for severe environmental pollution and has been threatening the aquatic ecosystem. In this study, kaolin-supported silver nanoparticle (Ag-NP) composites were synthesized by a facile two-step adsorption-reduction method through the reduction of silver ions adsorbed onto locally available, inexpensive, and easily pretreated kaolin surfaces by using sodium borohydride (NaBH4) for the catalytic degradation of methylene blue (MB) dye in aqueous solution. The morphology, structure, surface area, and interaction of the synthesized materials were investigated by scanning electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller, and Fourier transform infrared spectroscopy, respectively. Characterization results showed the successful growth of Ag-NPs on the kaolin surface. To understand the catalytic degradation performance of the catalyst, batch experiments were carried out using MB dye as a model dye. The catalytic reduction tests confirmed the importance of Ag-NPs and the high catalytic activities of the synthesized Ag-NPs/kaolin composite toward MB dye reduction. The degradation results indicated that the increased Ag-NP content on the kaolin surface through repeating cycles could effectively enhance the removal of MB dye from an aqueous solution. The kinetic analysis of the MB dye degradation of the catalyst has fitted the pseudo-first-order kinetic model. More than 97% removal efficiency was still present after five reuse cycles, demonstrating exceptional stability and reusability of the composite. In conclusion, the Ag-NPs supported kaolin (Ag-NPs/kaolin) composite was found to be a promising catalyst for the excellent catalytic activity to reduce a model dye MB from the aqueous solution in the presence of NaBH4 with catalytic efficiency higher than 97% and a reduction rate constant, k red, higher than 0.86 min-1.