Abstract
Kα X-ray emission spectra of manganese compounds have been measured using an ultimate-resolution Bragg spectrometer optimised for long-term high-statistics measurements. Energies corresponding to the peak positions of the Kα lines were measured to a precision of 10–20meV. Total line widths of the Kα1 and Kα2 components and their asymmetry have been determined to about 50meV. A model-free parametrisation of the line pattern corrected for the spectrometer response may serve as testing ground for detailed theoretical considerations.
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