Abstract
Shifts and widths of the K-absorption edge of cobalt in a specifically chosen variety and number of complexes involving donor atoms like nitrogen, oxygen and sulphur have been measured using a bent crystal spectrograph. The expected change in ionic/ covalent character of the metal-ligand bond in these complexes on the basis of Pauling's electronegativities and also observed from the optical spectra (where known) appears to be reflected in their X-ray edge-shifts and widths.
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