Joule-Heated Layered Double Hydroxide Sponge for Rapid Removal of Silica from Water.

Abstract

Dissolved silica is a major concern for a variety of industrial processes owing to its tendency to form complex scales that severely deteriorate system performance. In this work, we present a pretreatment technology using a Joule-heated sponge to rapidly remove silica from saline waters through adsorption, thereby effectively mitigating silica scaling in subsequent membrane desalination processes. The adsorbent sponge is fabricated by functionalizing two-dimensional layered double hydroxide (LDH) nanosheets on a porous, conductive stainless-steel sponge. With the application of an external voltage of 4 V, the Joule-heated sponge achieves 85% silica removal and 95% sponge regeneration within 15 min, which is much more efficient than its counterpart without Joule-heating (360 min for silica adsorption and 90 min for sponge regeneration). Material characterization and reaction kinetics analysis reveal that electrostatic interactions and "memory effect"-induced intercalation are the primary mechanisms for silica removal by the LDH nanosheets. Moreover, Joule-heating reduces the boundary layer resistance on nanosheets and facilitates intraparticle diffusion of dissolved silica, thereby increasing silica removal kinetics. Joule-heating also enhances the release of silicate ions during the regeneration stage through exchange with the surrounding anions (OH- or CO32-), resulting in a more efficient sponge regeneration. Pretreatment of silica-rich feedwaters by the Joule-heated sponge effectively reduces reverse osmosis membrane scaling by amorphous silica scale, demonstrating great potential for silica scaling control in a broad range of engineered processes.