Abstract

This study presents the first near-field measurements of interactions between reaction layers and water mist droplets suppressing a buoyant turbulent diffusion flame that is representative of a fire. Joint Mie scattering and OH-PLIF are employed at a high repetition rate of 400 Hz to image the droplet field and OH structure, which are deemed here to approximate the high-temperature reaction zone. Compressed natural gas (CNG) buoyant diffusion flames are stabilised on the Sydney Turbulent Buoyant Fire Burner, which is surrounded by a low-velocity air co-flow that is seeded with fine water mist droplets (d32 ∼ 50 µm). The water mist is doped with varying concentrations of metal alkali salts (NaHCO3, KHCO3) that release radical scavenging molecules, providing enhanced suppression capabilities through chemical inhibition in addition to the quenching effect from the water droplets. The spray boundary condition across the wind tunnel exit plane is quantified using Phase Doppler Interferometry. Flame extinction limits are measured by defining the critical condition at which the flame destabilises and lifts off the burner exit plane. A stability map is developed to quantify suppression efficacy in terms of the water mist flow rate and inhibitor concentration. Joint Mie-OH images of selected cases at varying extinction levels show that the addition of inhibitor introduces frequent breakages in the OH layers, marking regions of local extinction and reignition. Large mass fractions of inhibitor in the water, which, once evaporated, produces excess salt crystals in the local extinction zones that causes streaks of salt clouds that line both the lean and rich side of the flame. The chemical scavenging effects of the OH radical by NaHCO3 and KHCO3 is quantified by evaluating the reduction of the mean OH fluorescence signal in the flame at varying locations. Probability density functions for the OH area characterise local extinction in the flame due to the radical scavengers. The order of OH radical depletion and localised extinction in the flame due to the water mist follows: KHCO3 > NaHCO3 > H2O.

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