Abstract
AbstractRechargeable aqueous zinc batteries are promising for large‐scale energy storage due to their low cost and high safety; however, their energy density has reached the ceiling based on conventional cathodes with a single cationic redox reaction mechanism. Herein, a highly reversible cathode of typical layered vanadium oxide is reported, which operates on both the cationic redox couple of V5+/V3+ accompanied by the Zn2+ storage and the anionic O–/O2– redox couple by anion hosting in an aqueous deep eutectic solvent electrolyte. The reversible oxygen redox delivers an additional capacity of ∼100 mAh g–1 at an operating voltage of ∼1.80 V, which increases the energy density of the cathode by ∼36%, endowing the cathode system a record high energy density of ∼506 Wh kg–1. The findings highlight new opportunities for the design of high‐energy zinc batteries with both Zn2+ and anions as charge carriers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.