Janus Membrane with Hydrogel-like Coating for Robust Fouling and Wetting Resistance in Membrane Distillation

Abstract

Membrane distillation (MD) is a promising technique for water reclamation from hypersaline wastewater. However, fouling and wetting of the hydrophobic membranes are two prominent challenges for the widespread application of MD. Herein, we developed an antiwetting and antifouling Janus membrane comprising a hydrogel-like polyvinyl alcohol/tannic acid (PVA/TA) top layer and a hydrophobic polytetrafluoroethylene (PTFE) membrane substrate via a facile and benign strategy combining mussel-amine co-deposition with the shrinkage-rehydration process. Interestingly, the vapor flux of the Janus membrane was not compromised, though a microscale PVA/TA layer was introduced, possibly due to the high water uptake and reduced water evaporation enthalpy of the hydrogel-like structure. Moreover, the PVA/TA-PTFE Janus membrane sustained stable MD performance while treating a challenging saline feed containing surfactants and mineral oils. The robust wetting resistance arises from the synergistic effects of the elevated liquid entry pressure (1.01 ± 0.02 MPa) of the membrane and the retardation of surfactant transport to the substrate PTFE layer. Meanwhile, the hydrogel-like PVA/TA layer hinders oil fouling due to its strongly hydrated state. Furthermore, the PVA/TA-PTFE membrane exhibited improved performance in purifying shale gas wastewater and landfill leachate. This study provides new insights into the facile design and fabrication of promising MD membranes for hypersaline wastewater treatment.