Abstract

The electron-paramagnetic-resonance spectrum of ${\mathrm{Pt}}^{3+}$ was studied in single crystals of MgO. The spectrum exhibits a static Jahn-Teller effect with $\frac{\overline{\ensuremath{\delta}}}{3\ensuremath{\Gamma}}\ensuremath{\gtrsim}5$ and the first excited vibronic singlet is $^{2}A_{1}$. A theoretical estimation of the spin-Hamiltonian parameters yielded values very close to those obtained experimentally.

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