Abstract
The structural states of the semiconductors Zn1−xNixSe (x=0.0025) and Zn1−xCrxSe (x=0.0029) are investigated by the method of thermal neutron diffraction. Large-scale shear displacements of the atoms of the ZnSe lattice are observed, presumably brought on by the Jahn-Teller ions Cr2+ and Ni2+. The results of a study of the impurity heat capacity of the solid solutions Zn1−xMxSe (M=Cr2+,Ni2+) in the temperature interval 1.8–20K are presented. A heat-capacity method for determining the energy of intracenter transitions in these systems is described and employed. The role of the Jahn–Teller effect in the formation of the low-energy excited states of 3d ions in ZnSe is discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
