Abstract
Abstract Zinc 31,131-dihydroxychlorin lacking an exo-five-membered E-ring was prepared as a model of natural bacteriochlorophyll-d possessing 31-OH and 13-C=O groups. The synthetic zinc complex has the 13-CH2OH instead of the 13-C=O and self-aggregated in a nonpolar organic solvent, giving slipped and π-overlapped molecular stackings (J-aggregates) with red-shifted and broadened electronic absorption bands. For the intermolecular interactions among the J-aggregates, coordination bonding of the 31-OH (not 131-OH) with the central Zn was utilized.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
