Abstract

Eine kupferkatalysierte asymmetrische allylische Boronierung (AAB) ermöglicht den Zugang zu syn- und anti-1,2-Diolen. Die Methode erleichtert eine iterative Strategie zur Synthese von Polyolen (siehe Schema), wie z. B. vollständig differenziertes L-ribo-Tetrol und geschütztes D-arabino-Tetrol. P=Schutzgruppe.

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