Abstract

A family of acrylate-based isotropic Liquid Crystal Elastomers (LCEs) exhibit stress- and strain-optic coefficients orders of magnitude greater than conventional polymeric and photoelastic material...

Highlights

  • IntroductionTheir inherent anisotropy leads to a variety of unique properties, including switchable geometries and soft elasticity

  • Liquid crystal elastomers (LCEs) are remarkably responsive and biosimilar materials

  • We examined the phase behaviors of each LCE precursor optically and via Differential Scanning Calorimetry (DSC) scans performed between 0 and 50 °C

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Summary

Introduction

Their inherent anisotropy leads to a variety of unique properties, including switchable geometries and soft elasticity These outstanding features of LCEs have resulted in many exciting proposed applications, including photoactuated microrobots, novel chemical sensors, substrates for flexible electronics, and variable irises to name but a few.[1−4] recently, some LCEs were found to exhibit negative Poisson’s ratio, making them the first synthetic molecular auxetics.[5] Despite their wide range of possible applications, LCEs have rarely been considered as optical strain sensors. Photoelasticity, which can map stresses and strains via the photoelastic effect, offers instantaneous and direct measurement of stress and strain distributions across complex physical objects and devices.[11−13] Examples include the use of transmission photoelasticity to determine how stresses percolates through masonry walls modeled by transparent poly(methyl methacrylate) bricks and reflection photoelasticity to study the deformations of masonry columns and even dental prosthetics in vivo.[14−16]

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