Abstract
The isotopically invariant Dunham parameters U mj , Δ mj H and Δ mj Cl were determined by simultaneously fitting the line centers of vibration-rotation transitions of six isotopic HCl forms in the ground electronic state. Fitting included relations between U mj values. The parameters of the isotopically invariant potential of HCl were determined using independent U m0 and U m1 values. The contributions to the vibrational terms of H35Cl caused by violation of the Born-Oppenheimer approximation were calculated.
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