Abstract

1. Dimethylsulfonium cyclopentadienylide tricarbonylmolybdenum undergoes isotopic hydrogen exchange in neutral media, the exchange rate being 130 times greater than that observed for the corresponding chromium complex. 2. There is a one-order variation in the rate of isotopic hydrogen exchange in the tricarbonyl complexes of molybdenum with dimethylaminofulvene, dimethylsulfonium cyclopendadienylide, and triphenylphosphonium cyclopentadienylide.

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