Isotopic geochemical characteristics of two types of carbonate concretions of Chang 7 member in the middle-upper Triassic Yanchang Formation, Ordos Basin, Central China

Abstract

Abstract Carbonate concretion is an authigenic aggregation of minerals commonly found in sandstone and shale, especially in organic-rich shale. In the outcrop, large number of carbonate concretions developed in Chang 7 member in Tongchuan. Those concretions were studied in terms of stable isotope, clumped isotope to delineate its origin and sedimentary environment. Two types of concretions are identified. Type A concretionsmainly distribute in organic-rich shale. This concretion was divided into the inner circular layer and the outer circular layer. In the inner circular layer, the value of δ13C‰(VPDB) is 9.98‰~14.19‰, and the value of δ18O‰(VPDB) is −13.32‰~-10.07‰. On the contrary, the δ13C and δ18O value of outer circular layer are4.74‰~-0.59‰,-17.86‰~-15.59‰ respectively. The formation palaeotemperature of different parts of concretion ranged from 28.6 to 76.5 °C. This may be due to methanogenesis arising from bacterial activities in the fermentation zone, and the fractional distillation of carbon isotope of organic matter was caused by the methane bacterial activities. The calcite and dolomite spherulites in carbonate concretions may be due to the calcilization and dolomitization of cyanobacteria in the early diagenesis. The type B concretions were distributed in the fine sandstone, silty sandstone, and silty mudstone. The internal structure of concretions is uniform. The carbon isotopic values were negative, and δ13C was −5.019~-12.013‰, and the δ18O values was −17.6~-19.281‰. The value of 87Sr/86Sr was in the range of 0.710072–0.710392. The temperature was established at 60.4 °C through clumped isotopes analysis. Based on isotopic analysis, the formation palaeotemperature at different parts of concretion was 55.4–65.6 °C. The origin of the concretion may be related to dehydroxylation in diagenesis, formed in the early-middle stage of diagenesis.