Isotope radon measurement method to identify spontaneous combustion regions in coal gangue hills: case study for a coal mine in China

Abstract

ABSTRACT Long-term accumulation of coal gangue hill has a high risk of spontaneous combustion, and the toxic and harmful gases emitted by spontaneous combustion seriously pollute the atmosphere. The key to managing the spontaneous combustion fire of coal gangue hill lies in the accurate measurement of fire source location. However, measuring the fire source location of surface coal gangue hill lacks experimental and empirical research. In this paper, an oxidation warming experiment was conducted on the coal gangue samples, and the law of radon gas exhalation from coal gangue under different temperatures was analyzed. At the same time, surface thermometry and isotope radon measurement were applied to measure the high-temperature areas inside the gangue hill, and the measurement results were compared. The experimental results show that as the temperature of gangue increases, the amount of radon gas exhalation in gangue shows a changing trend of rising first and then decreasing. The radon exhalation from coal gangue can be divided into three stages. In the I stage (30 ~ 100°C), the evaporation of pore water in coal gangue leads to the exhalation of radon in water, causing the increase of radon concentration; in the II stage (100 ~ 350°C), the coal gangue is pyrolyzed at high temperature, and a large amount of radon is exhalated from the closed pores; in the III stage (350 ~ 450°C), after the first two stages of radon release, the number of radon atoms in this stage decreases, leading to a rapid decrease of radon concentration. The field measurement results show that compared with the surface thermometry method, the isotope radon measurement method is less disturbed by external conditions, and the circled fire area is more accurate, which has essential theoretical significance and practical application value for the accurate measurement of fire source location in coal gangue hill.