Abstract

Recent studies on hydrogen isotope transfer reactions in the gas phase chemistry of thermal and excited species, ionic systems, and reactive scattering and theoretical attempts made to rationalize experimental observations are critically reviewed. Topics discussed are bimolecular reactions, termolecular reactions, unimolecular decomposition reactions, molecular beam scattering, chemiluminescence and laser reactions, ion-molecule reactions, and unimolecular ionic decomposition reactions. In the review of theory theoretical kinetic isotope effect calculations, trajectory calculations, and quantum chemical calculations are considered. 199 references. (JSR)

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