Abstract
Conformational equilibrium isotope effects (in J mol −1) have been measured for deuteriation of one methyl or methylene group in the trans stereoisomers of 1,3-dimethylcyclohexane (−46 ±10), 2,6- (−80 ±28) and 3,5-dimethylcyclohexanone (−40 ±15), and 3-methyl- (48 ±3) and 3-hydroxymethyl 1-trifluoromethylcyclohexane (45—49 ± 3 in toluene, acetone or methanol). The observed effects are independent of solvent for the hydroxymethyl group The isotope effects for the methyl group in trans- 4 are proportional to the number of deuterium atoms.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
