Abstract

Abstract It is well established that electrical and magnetic properties of crystals are strongly influenced by structural phase transitions. The strong charge transfer complexes such as tetrathiofulvalene-tetracyanoquinodimethan (TTF-TCNQ) have been intensely studied(1) but much less is known concerning weak charge transfer complexes and the influence of solid-solid transitions on their properties. Typical examples of some weak charge transfer complexes are the 1:1 complexes formed between aromatic donors (e.g. naphthalene) and aromatic acceptors (e.g. 1,2,4,5 tetracyanobenzene, TCNB).

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