Abstract
The isothermal, non‐oxidative, two‐step conversion of CH4 to C2+ hydrocarbons was investigated over unsupported and supported Pt and Ru catalysts at moderate temperatures and elevated pressures. The single‐cycle specific activity (µmol C2+/gcat) and total product yield (µmol C2+/µmol surface metal) for Ru powder at 430 K were significantly higher than for Pt powder at 503 K. The activity and total product yield for mixed metal oxide (MMO)‐supported Ru were significantly less than for Ru powder; however, Pt/MMO exhibited similar activity and product yield in comparison to Pt powder. The formation of methylbutane and methylpentane increased with increasing pressure over Ru/MMO. However, increasing pressure favored the formation of C4 species over Pt/MMO.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.