Abstract
A summary of both classical (isothermal) and adiabatic theories of nucleation is presented. Using experimentally determined parameters, such as viscosity, specific heat, glass transition temperature (Tg), melting temperature (Tf) and heat of fusion, the temperatures of maximum crystal nucleation rates, Tmax, were calculated for several glass forming systems and compared with experimental data. It is shown that both theories give a good estimate for Tmax. For systems which do not show volume (homogeneous) nucleation, Tmax is lower than Tg. For systems which show volume nucleation, Tmax >Tg. It is concluded that both theories can be used to predict the occurrence of internal crystal nucleation in glasses and that, in general, a high value of Tg (Tg/Tf > 0.58) indicates the absence of internal nucleation.
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