Abstract
Isosteric heats of sorption of n-hexane on M x Na 56-2 x Y zeolites (M = Co, Ni, Zn, Cd) were determined from isotherms at two temperatures (288 and 298 K). It was found that the exchange of Na + ion in NaY with bivalent cations (Co, Ni, Zn, Cd) significantly alters the sorption characteristics of NaY zeolites. The specific influence of exchanged cations on isosteric heats of sorption of n-hexane depends on the size and electronic configuration of the cation.
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