Abstract
The title compound, [Na(C4H7OS2)(C12H8N2)2], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal antiprism. A number of π–π stacking interactions involving the phen rings help to consolidate the crystal packing (centroid–centroid distances lie in the range 3.338–3.443 Å).
Highlights
The title compound, [Na(C4H7OS2)(C12H8N2)2], is monomeric, with the Na atom chelated by the S atoms of an ipropylxanthate ligand and the N atoms of two 1,10phenanthroline ligands
A number of – stacking interactions involving the phen rings help to consolidate the crystal packing
As a continuation of our interest in sulfur-containing ligands, in this paper we report the synthesis and structural characterization of the title compound, (I)
Summary
R factor = 0.046; wR factor = 0.127; data-to-parameter ratio = 13.7. The title compound, [Na(C4H7OS2)(C12H8N2)2], is monomeric, with the Na atom chelated by the S atoms of an ipropylxanthate ligand and the N atoms of two 1,10phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal antiprism. A number of – stacking interactions involving the phen rings help to consolidate the crystal packing
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