Isomorphous Substitution of Gallium into MFI-Framework Zeolite Increases 2,5-Dimethylfuran to Aromatics Selectivity and Suppresses Catalyst Deactivation

Abstract

The valorization of biomass-derived molecules into commodity chemicals is important for the transition to renewable feedstocks. The model platform molecule 2,5-dimethylfuran (2,5-dmf) can be converted into value-added aromatics such as benzene, toluene, and xylenes (BTX) over zeolite catalysts. To explore the role of the zeolite acid site(s) in BTX selectivity, gallium has been isomorphously substituted into the framework, resulting in a Ga-silicate. Compared to the ZSM-5 counterpart, this modification shows enhanced benzene selectivity as well as resistance to deactivation by coke in continuous catalytic performance tests.