Abstract
[CH 3CHNH 3] +. and [CH 2CH 2NH 3] +. ions exist as distinct, stable species in the gas-phase. These ions are formed from a variety of precursors, and they can be characterized by their unimolecular and collision-induced reactions. The properties of deuterium labeled analogs confirm the proposed structures. Evidence that stable C 3H 9N +. ions with unconventional structures also exist is presented; these and other amine ion isomers are formed from inter alia, alkylamine molecular ions in the ion source.
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