Abstract
Lithium diisopropylamide (LDA) induced metalation reaction of styrenes with para substituents such as 4-methylstyrene (MST), 4-((trimethylsilyl)methyl]styrene (SMS), and 4-((dimethylamino)methyl]styrene (AMS) to form vinylbenzyllithium (VBL) derivatives. VBL derivatives initiated isomerization polymerizations to form oligomers with a polymerizable vinyl end and with functional groups such as amino groups and trimethylsilyl groups in the side chain. Cooligomerization of the 4-substituted styrenes gave macromonomers with a predicted extent of functional groups in the side chain
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