Abstract
1. Cyanosilylated acrolein and 2-ethoxyacrolein isomerize in the presence of secondary amines and react with an excess of the latter to form derivatives of propionamide and N-substituted aminosilanes. 2. Unlike 1-cyano-1-trimethylsiloxy-2-ethoxy-2-propene, 1-cyano-1-trimethylsiloxy-2-propene is thermally stable and does not isomerize under the action of the Speier catalyst, colloidal nickel, ZnI2, or pyridine.
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