Abstract
Charged species structurally related to several isomers of Cl2O2, of considerable importance in atmospheric chemistry, were obtained by chemical ionization (CI) and characterized by collisionally activated dissociation (CAD) mass spectrometry. The ClOClO+ and [Cl2-O2]+ species were prepared by positive ion Cl2/CI of ClO2 and O2, respectively, whereas the ClClO2+ isomer proved an elusive species of considerably lower stability. The ClClO2− anion was obtained from the negative ion Cl2/CI of ClO2. The formation process, structure and stability of the ions are discussed in connection with available theoretical results and related to the recent preparation of (Cl2O2)+SbF6− and (Cl2O2)+Sb2F11− salts in the solid phase. Copyright © 1999 John Wiley & Sons, Ltd.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
