Abstract
Phenanthrene ·Ar n van der Waals clusters exhibit spectroscopically distinct isomers for n=2 and 4. The ionization potentials (IP) of these isomers differ by 33 ( n=2) and 56 cm −1 ( n=4), or about 25% of the total IP shift induced by the cluster. Based on this IP difference, isomer-selective ionization and electronic spectroscopy have been performed.
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