Abstract
Abstract 8-Methyl-2-(trimethylsiloxy)tricyclo[5.3.1.03,8]undec-2-ene (11) was prepared and characterized, which is the first example of the isolable strained bridgehead enol ether of a bicyclo[3.3.1]nonan-2-one system. The reactions of 11 with electrophiles readily occurred at the C-3 bridgehead position.
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