Abstract
16-Oxoestradiol (IV), two pairs of isomeric 2-and 3-methyl ethers of 2-hydroxyestriol (II, III) and 2-hydroxy-16-oxoestradiol (V, VI) have been characterized as biliary glucuronide metabolites of estriol in the rat. This is the first report on in vivo formation of catechol estrogen having the 16-oxo-17β-ol structure.
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