Abstract
Abstract In order to study the performance of organometallic complexes in the telomerization of butadiene with methanol in aqueous medium, we synthesized and characterised hydrosoluble palladium complexes. [(π-allyl)Pd(TPPTS) 2 ] + Cl − complex exhibited strong stability as no degradation was observed after storage at room temperature under air atmosphere for weeks. TON’s up to 36 000 were achieved at 50 °C.
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