Abstract
One-dimensional, two-dimensional and three-dimensional Ni-containing metal-organic coordination polymer (1D-Ni, 2D-Ni and 3D-Ni MOCP) catalysts were solvothermally synthesized and used for isomerization of isobutene. These catalysts showed the same conversion of isobutene and selectivity for 2-butene as homogeneous catalysts. At the same time, 1D-Ni catalyst evacuated at 100 °C revealed the conversion of isobutene and selectivity to 2-butene were up to 89.2% and 100.0%, respectively. Moreover, the results demonstrated that the conversion of isobutene was different depending on metal coordination mode, dimension of coordination polymer, and the reaction pressure. In addition, The MOCP catalysts were relatively environmentally friendly, and easily recovered and recycled. Finally, the mechanism of metal hydride addition elimination was proposed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
