Abstract
Isobaric vapor−liquid equilibria (VLE) have been determined for the binary systems of dimethyl carbonate (DMC) + ethanol, dimethyl carbonate + diethyl carbonate (DEC), dimethyl carbonate + propylene glycol (PG), and dimethyl carbonate + propylene carbonate (PC) under atmospheric pressure in an Ellis equilibrium still. The data have been checked by employing a global statistic thermodynamic consistency test and also have been correlated by means of both the Wilson equation and the NRTL equation. The experimental results demonstrated that the systems of DMC + ethanol and DMC + PG show strong positive deviations from ideality and that the systems of DMC + DEC and DMC + PC are close to ideality.
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