Abstract
Isobaric vapor−liquid equilibria for both 1-octene + propenoic acid and 2-butyl propenoate + propenoic acid systems have been determined at 6.67 kPa in a small-capacity recirculating still. Results were found to be thermodynamically consistent by using the L−W method of Wisniak and they were satisfactorily correlated with the van Laar, Wilson, and UNIQUAC equations, considering propenoic acid as an associating compound in both liquid and vapor phases.
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