Is the unexpected behaviour of the resolved K 3[Cr III(C 2O 4) 3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [Mn IICr III(C 2O 4) 3 NEt( n-Pr)( n-Bu)( n-C 5H 11)] network?

Michel Gruselle,Cyrille Train,Nikolai S Ovanesyan,Viktor D Makhaev,Christine Cordier

doi:10.1070/mc2004v014n06abeh002035

Is the unexpected behaviour of the resolved K 3[Cr III(C 2O 4) 3] in aqueous solution responsible for the formation of pure chiral solid phase of a two-dimensional (2D) [Mn IICr III(C 2O 4) 3 NEt( n-Pr)( n-Bu)( n-C 5H 11)] network?

Michel Gruselle, Cyrille Train + Show 3 more

https://doi.org/10.1070/mc2004v014n06abeh002035

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Journal: Mendeleev Communications	Publication Date: Jan 1, 2004
Citations: 3

Affiliation: Sorbonne Université, French National Centre for Scientific Research, Université Paris Cité, Délégation Paris 7

#Pure Solid Phase #Formation Of Solid Phase + Show 8 more

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Abstract

Racemic and resolved [CrIII(C2O4)3]K3 dissolved in water were investigated by IR spectroscopy. Compared to the racemic compound, the spectrum of the resolved one exhibits additional peaks, which have a complex temporal evolution. These peaks are attributed to water molecules coordinated to the metal ion and tentatively related to the formation of a pure chiral solid phase of two-dimensional (2D) oxalate-based Mn–Cr networks starting from partially resolved [CrIII(C2O4)3]3–.

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