Abstract
Several lithium Ruddlesden–Popper compounds are investigated by TEM (ED and HREM) in the series Li2Lax (Nb2n−3xTi3x−n)O3n+1 (n=2, 3, and 4, for x=0.833, 1.78, and 2.25, respectively) and Li2Sr1.5 (Nb3−xFex) O10−x (for n=3; x=0 and 0.115). These studies confirm the crystal structures previously established from single crystal X-ray diffraction data: they consist of perovskite layers separated by Li+ ions in distorted tetrahedral coordination. After the HREM study, for all the examined compounds, an irreversible structural change is evidenced leading to a unique model (space group I4/mmm) characterized by the preservation of the perovskite layers and by a substantial shrinking of the c parameter ( perpendicular to the perovskite slabs). In the hypothesis of the conservation of the cells contents, this phenomenon is explained by a concomitant change in the Li+ coordination which becomes octahedral.
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