Abstract

AbstractViscose‐based activated carbon fiber (VACF) was modified with acrylonitrile (AN) by γ‐irradiation‐induced grafting polymerization. Effects of the grafting conditions, such as concentrations of AN and divinylbenzene (DVB), pH value, and solvent on the grafting process were studied. The physicochemical properties of the fibers were characterized. The results show that AN can be effectively grafted onto the surface of VACF with the addition of DVB. The grafting yield is higher than 12% according to thermogravimetric (TG) analysis. The study shows that DVB can improve the grafting degree of AN in the form of grafting chains or agglomerate materials. After grafting modification, VACF shows a small decrease in the specific surface area. Copyright © 2009 John Wiley & Sons, Ltd.

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