Abstract

Most irradiation studies in the hydrogen bonded ferroelectrics have been concentrated on the transient defects induced by ionising radiation, such as ultraviolet (UV) light, where the defects are closely related to the optical properties. But heavy ion beam irradiation effects have rarely been studied. The structural, optical, and non-linear optical properties of the doped crystals were analyzed with the characterization studies, such as powder XRD, UV-Visible and second harmonic generation (SHG) measurements, respectively. The results for doped KDP crystal were compared with the results of the pure KDP crystals. The experiment results showed that Li3+ irradiation leads to the development of a well-defined surface H peak in dye doped KDP crystals. The stability of KDP single crystal was improved by doping organic dyes. The nano-islands of dye in KDP were likely to be dissolved and enhance the non-linear optical properties of these materials.

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