Iron(III) Oxide Nanoparticles in the Thermally Induced Oxidative Decomposition of Prussian Blue, Fe4[Fe(CN)6]3

Abstract

The thermally induced decomposition of Prussian Blue, Fe4[Fe(CN)6]3 (PB), was studied in air at 250 and 350 °C. Amorphous Fe2O3 nanoparticles, cubic bixbyite β- and cubic spinel γ-Fe2O3 (maghemite) polymorphs, have been identified as the products of the decomposition under different reaction conditions. 57Fe Mossbauer spectroscopy, XRD, AFM, TEM, quasielastic light scattering method (QELS) of particle size analysis, BET surface area, and magnetization measurements were used to understand the influence of the PB particle size and oxidation conditions on the decomposition mechanism at 250 and 350 °C. At a minimum decomposition temperature of 250 °C, amorphous Fe2O3 nanoparticles were formed with the size ranging from 1 to 4 nm and large surface area of 400−200 m2/g in dependence on the PB particle size. Such small amorphous Fe2O3 nanoparticles were obtained by the solid-state route for the first time. At 350 °C, cubic β-Fe2O3 and γ-Fe2O3 polymorphs were identified and their contents were found to be strongl...