Abstract

The isothermal kinetic analysis of sodium ferrite formation by reaction between Na 2O 2 and FeSO 4 shows that the rate-controlling step is nuclei growth. This mechanism differs from that established in the case of the BaO 2-FeSO 4 system (diffusion-controlled). The appearance of Fe 2O 3 as intermediate here might be the primary cause of this different behaviour. Non-isothermal procedures appear unsuccessful in our analysis of the reaction between Na 2O 2 and FeSO 4.

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