Abstract
AbstractThe combination of diiron nonacarbonyl and dimethylamine gives an active catalyst for displacement of allylic acetate by diethyl methylmalonate. It was found that among a series of amines, only dimethylamine and morpholine were efficient promoters of the reaction. Solvents such as dimethylformamide (DMF) and N‐methylformamide were much superior to tetrahydrofuran, dichloromethane, and ethanol.
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